By Richard G. Schweiger (Eds.)
content material: Monosulfate esters of L-ascorbic acid / Donald W. Lillard, Jr. and Paul A. Seib --
Glucosinolates and different certainly happening O-sulfates / Anders Kjaer --
Sulfate ester teams as strength informational regulators in glycoproteins / P.W. Kent, C.J. Coles, J.R. Cooper, and N.R. Mian --
reviews at the synthesis of sulfur-containing glycolipids ("sulfogylcolipids") / Roy Gigg --
Spectrofluorimetric tools for estimating and learning the interactions of polysaccharides in organic structures / R.B. Cundall, D. Murray, and G.O. Phillips --
Sulfated glycosaminoglycans received via chemical amendment of polysaccharides / Derek Horton and Taichi Usui --
Heparin derivatives of excessive molecular weight / L. Mester, A. Amit Amaya, and M. Mester --
Enzymatic formation and hydrolysis of polysaccharide sulfates / Kalyan ok. De, Kazuhiko Yamamoto, and Roy L. Whistler --
a few novel tools and leads to the sulfation of polysaccharides / Kenneth B. Guiseley --
Sodium cellulose sulfate through cellulose nitrite / Richard G. Schweiger --
response of starch with the chlorosulfonic acid-formamide reagent / F. Schierbaum and ok. Kördel --
Sulfonic acid and sulfomethyl-containing graft co-polymers of xanthan gum / I.W. Cottrell, J.L. Shim, G.H. most sensible, and R.A. Empey --
Sulfated polysaccharides metabolized via the marine chlorophyceae : a evaluate / Elizabeth Percival --
Sulfated polysaccharides of the rhodophyceae : a assessment / Elizabeth Percival --
Sulfated fucose-containing polysaccharides from brown algae : structural good points and biochemical implications / Darrell G. Medcalf --
Co-ion and counter-ion interactions with sulfonated polysaccharides / Margaret Tomasula, Nancy Swanson, and Paul Ander --
interplay of sulfated polysaccharides with counter-ions / G. move, G.O. Phillips, D.J. Wedlock, and R.G. Morley.
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Extra resources for Carbohydrate Sulfates
C h o l i n e sulphate ,12 a c c u m u l a t e s , to the extent of m o r e than o n e - t h i r d of the t o t a l amount of sulphate fed, i n the r o o t s of s u l p h u r - d e f i c i e n t p l a n t s of c o r n , b a r l e y , and s u n f l o w e r , e v e n u n d e r s t e r i l e c o n d i t i o n s . In n o n - d e f i c i e n t r o o t s , and i n a l l l e a v e s , it a c counts f o r 5-15 % of the t o t a l , s o l u b l e s u l p h u r compounds. 2 a s an e f f e c t i v e t r a n s p o r t agent f o r p a s s a g e t h r o u g h the c e l l m e m b r a n e h a s b e e n s u g g e s t e d (11).
Fortschr. Chem. Org. , (1960) 18, 122. Ettlinger, M. G. and Kjær, A. in "Recent Advances in Phytochemistry", Vol. I, p. 89, Mabry, T. , Alston, R. E. and Runeckles, V. , Appleton-Century-Crofts, New York, Ν. Y. (1968). 28 3. 4. ch002 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. CARBOHYDRATE SULFATES Kjær, A. in "Chemistry in Botanical Classification", Nobel Symposium 25, p. 229, Bendz, G. , Academic Press, New York and London (1974). Kjær, A. in "The Biology and Chemistry of the Cruciferae", p.
I n the h e p a r i n s e r i e s , de Ν-sulphation o f t h a t m a t e r i a l o r o f h e p a r i t i n sulphate d i d not b r i n g about change o f conformation, though complete desulphation caused the h e l i c a l s t r u c t u r e to disappear. The primary s t r u c t u r e p l a y s a d e c i s i v e p a r t i n conformational determination, the l i n k e d p o s i t i o n o f each e s t e r sulphate being important i n r e l a t i o n to hydrogen-bonding c a p a b i l i t y . Elegant X-ray a n a l y t i c a l s t u d i e s by Rees (1969) and by A t k i n s and Laurent (1973) have e s t a b l i s h e d f i n e d e t a i l s o f ordered conformation o f these mucopolysaccharides.
Carbohydrate Sulfates by Richard G. Schweiger (Eds.)